Acid Rain (Causes and Effects)

What is Acid Rain?

Acid rain, or acid deposition, is a broad term that includes any form of precipitation with acidic components, such as sulfuric or nitric acid that fall to the ground from the atmosphere in wet or dry forms.  This can include rain, snow, fog, hail or even dust that is acidic.  

What Causes Acid Rain?

 

Acid rain results when sulfur dioxide (SO₂) and nitrogen oxides (NO_X) are emitted into the atmosphere and transported by wind and air currents.  The SO₂ and NO_X react with water, oxygen and other chemicals to form sulfuric and nitric acids.  These then mix with water and other materials before falling to the ground.

While a small portion of the SO₂ and NO_X that cause acid rain is from natural sources such as volcanoes, most of it comes from the burning of fossil fuels.  The major sources of SO₂ and NO_X in the atmosphere are:

• Burning of fossil fuels to generate electricity.  Two thirds of SO₂ and one fourth of NO_X in the atmosphere come from electric power generators.
• Vehicles and heavy equipment.
• Manufacturing, oil refineries and other industries.

Winds can blow SO₂ and NO_X over long distances and across borders making acid rain a problem for everyone and not just those who live close to these sources. 

Acid rain refers to a mixture of deposited material, both wet and dry, coming from the atmosphere containing more than normal amounts of nitric and sulfuric acids. Simply put, it means rain that is acidic in nature due to the presence of certain pollutants in the air due to cars and industrial processes. It is easily defined as rain, fog, sleet or snow that has been made acidic by pollutants in the air as a result of fossil fuel and industrial combustions that mostly emits Nitrogen Oxides (NOx) and Sulfur Dioxide (SO2). Acidity is determined on the basis of the pH level of the water droplets. Normal rain water is slightly acidic with a pH range of 5.3-6.0, because carbon dioxide and water present in the air react together to form carbonic acid, which is a weak acid. When the pH level of rain water falls below this range, it becomes acid rain.

When these gases react with water molecules and oxygen among other chemicals found in the atmosphere, mild acidic chemical compounds such as sulfuric and nitric acid are formed resulting to acid rain. Acid rain generally leads to weathering of buildings, corrosion of metals, and peeling of paints on surfaces. Erupting volcanoes contains some chemicals that can cause acid rain. Apart from this, burning of fossil fuels, running of  factories and automobiles due to human activities are few other reasons behind this activity.

Causes and History of Acid Rain

Acid deposition can be causes by natural sources like volcanoes, but it is mainly caused by the release of sulfur dioxide and nitrogen oxide during fossil fuel combustion.

When these gases are discharged into the atmosphere, they react with the water, oxygen, and other gases already present there to form sulfuric acid, ammonium nitrate, and nitric acid. These acids then disperse over large areas because of wind patterns and fall back to the ground as acid rain or other forms of precipitation.

The gases most responsible for acid deposition are a byproduct of electric power generation and the burning of coal. As such, man-made acid deposition began becoming a significant issue during the Industrial Revolution and was first discovered by a Scottish chemist, Robert Angus Smith, in 1852. In that year, he discovered the relationship between acid rain and atmospheric pollution in Manchester, England.

Although it was discovered in the 1800s, acid deposition did not gain significant public attention until the 1960s, and the term acid rain was coined in 1972. Public attention further increased in the 1970s when the New York Times published reports about problems occurring in the Hubbard Brook Experimental Forest in New Hampshire.

Effects of Acid Rain

After studying the Hubbard Brook Forest and other areas, researchers have found several important impacts of acid deposition on both natural and man-made environments.

Aquatic settings are the most clearly impacted by acid deposition though because acidic precipitation falls directly into them. Both dry and wet deposition also runs off of forests, fields, and roads and flows into lakes, rivers, and streams.

As this acidic liquid flows into larger bodies of water, it is diluted, but over time, acids can accrue and lower the overall pH of the body of water. Acid deposition also causes clay soils to release aluminum and magnesium further lowering the pH in some areas. If the pH of a lake drops below 4.8, its plants and animals risk death.

Aside from aquatic bodies, acid deposition can significantly impact forests.

As acid rain falls on trees, it can make them lose their leaves, damage their bark, and stunt their growth. By damaging these parts of the tree, it makes them vulnerable to disease, extreme weather, and insects. Acid falling on a forest’s soil is also harmful because it disrupts soil nutrients, kills microorganisms in the soil, and can sometimes cause a calcium deficiency. Trees at high altitudes are also susceptible to problems induced by acidic cloud cover as the moisture in the clouds blankets them.

Damage to forests by acid rain is seen all over the world, but the most advanced cases are in Eastern Europe. It’s estimated that in Germany and Poland, half of the forests are damaged, while 30% in Switzerland have been affected.

Finally, acid deposition also has an impact on architecture and art because of its ability to corrode certain materials. As acid lands on buildings (especially those constructed with limestone) it reacts with minerals in the stones sometimes causing them to disintegrate and wash away. Acid deposition can also cause concrete to deteriorate, and it can corrode modern buildings, cars, railroad tracks, airplanes, steel bridges, and pipes above and below ground.

As for some of the impacts of acid rain that can be grouped into: 

Effect on Public Health: When in atmosphere, sulfur dioxide and nitrogen oxide gases and their particulate matter derivatives like sulfates and nitrates, degrades visibility and can cause accidents, leading to injuries and deaths. Human health is not directly affected by acid rain because acid rain water is too dilute to cause serious health problems. However, the dry depositions also known as gaseous particulates in the air which in this case are nitrogen oxides and sulfur dioxide can cause serious health problems when inhaled. Intensified levels of acid depositions in dry form in the air can cause lung and heart problems such as bronchitis and asthma. 

Vegetation Cover and Plantations: The damaging effects of acid rain on soil and high levels of dry depositions have endlessly damaged high altitude forests and vegetation cover since they are mostly encircled by acidic fogs and clouds. Besides, the widespread effects of acid rain on ecological harmony have lead to stunted growth and even death of some forests and vegetation cover. 

Effect on Forests: It makes trees vulnerable to disease, extreme weather, and insects by destroying their leaves, damaging the bark and arresting their growth. Forest damage due to acid rain is most evident in Eastern Europe – especially Germany, Poland and Switzerland.

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Effect on Soil: Acid rain highly impacts on soil chemistry and biology. It means, soil microbes and biological activity as well as soil chemical compositions such as soil pH are damaged or reversed due to the effects of acid rain. The soil needs to maintain an optimum pH level for the continuity of biological activity. When acid rains seep into the soil, it means higher soil pH, which damages or reverses soil biological and chemical activities. Hence, sensitive soil microorganisms that cannot adapt to changes in pH are killed. High soil acidity also denatures enzymes for the soil microbes. On the same breadth, hydrogen ions of acid rain leach away vital minerals and nutrients such as calcium and magnesium. 

Effect on Architecture and Buildings: Acid rain on buildings, especially those constructed with limestone, react with the minerals and corrode them away. This leaves the building weak and susceptible to decay. Modern buildings, cars, airplanes, steel bridges and pipes are all affected by acid rain. Irreplaceable damage can be caused to the old heritage buildings.